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class="typo"> 苯基硅油是甲基硅油中部分甲基被苯基替代后的產物,無色或淡黃色通明油狀物。不僅僅是甲基硅油可以用于織物，對織物有影響，合成的苯基硅油關于織物也是有影響的。本文合成了幾種苯基硅油，測試了苯基硅油及由其組成的硅橡膠系統的歸納功能，研究了不同苯基硅油應用于織物處理的功能，分析了處理前后織物的功能及變化。<br />　　以甲基三甲氧基硅烷為質料，合成了高純度的甲基苯基二甲氧基硅烷。以該單體和二苯基二甲氧基硅烷為質料，徹底共水解后，以六甲基二硅氧烷為封端劑、三氟甲磺酸為催化劑，平衡縮合得到了各種苯基摩爾含量的甲基苯基硅油和二苯基硅油。<br />　　研究了兩種苯基硅油的苯基摩爾含量變化對硅油的功能影響，如熱穩定性、折射率、流變功能等。結果表明，關于二苯基硅油而言，當苯基摩爾分數為40％時折射率較高，達1.5435，摩爾分數為30%時熱穩定性較好。<br />　　以二苯基二甲氧基硅烷、二甲基二甲氧基硅烷為質料，1,3-二乙烯基四甲基二硅氧烷為封端劑，制得了乙烯基封端苯基硅油。以二苯基二甲氧基硅烷、二甲基二甲氧基硅烷、甲基二氯硅烷為質料，六甲基二硅氧烷為封端劑，合成了苯基含氫硅油。<br />　　將乙烯基封端苯基硅油和苯基含氫硅油兩種組份在催化劑成效下，交聯固化后得到硅橡膠。制備的薄膜在460nm紫外光下透光率較高可達97.14%。探索了不同苯基硅油組成的苯基硅橡膠系統功能變化規律，發現苯基硅橡膠的折射率與乙烯基封端苯基硅油分子量正相關。<br />　　然后，將幾種苯基硅油應用于織物處理，對比測試了處理前后織物機械功能、白度等，以及苯基硅油處理織物的牢度。研究發現，苯基硅油收拾后織物拉伸力普遍增強，但白度略有下降。用苯基硅油處理色布時，處理后色布的皂洗牢度、濕沖突牢度和日曬牢度均提高一級。<br />　　甲基硅油用于織物的柔軟收拾，添加織物的潤滑性，添加織物的滑爽感、豐滿度和彈性。而苯基硅油收拾后織物拉伸力普遍增強，但白度略有下降。用苯基硅油處理色布時，處理后色布的皂洗牢度、濕沖突牢度和日曬牢度均提高一級。 </div> </div> </div>  <div class="bot-mod-box mt10"> <div class="bot-mod-link"> <div class="bot-m-l"> <b>上一篇：</b> <a 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