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<div>　　苯基硅油發光二極管(LED)是一種電致發光固體器件。隨著技術的不斷創新和我國政策的引導，整個LED產品發展迅速，LED封裝行業同步發展。在包裝材料中，有機硅包裝材料以其優異的性能得到了業界的認可，成為發展較快、較有價值的包裝材料，顯示出很大的市場價值。</div><div>　　LED封裝是一種新型高性能液體硅膠，也稱光學封裝。在可見光區域保持高透光率，對紫外光具有高吸收率，提高照明設備的光輸出率和使用時間。</div><div>　　近年來，由于LED產業的快速發展，LED封裝材料的需求量越來越大。有機硅LED封裝膠以其優異的物理化學性能成為LED封裝材料領域的佼佼者。隨著能源危機的加劇，LED產業將繼續增長。因此，LED封裝材料的市場潛力很大。大功率LED封裝材料對原材料的透光率和折射率要求很高。苯基硅油已經成為LED封裝膠的重要組成部分。隨著苯基摩爾分數的增加，有機硅材料的耐高溫性、耐輻射性和折射率都得到了提高，苯基硅油在LED封裝膠中的地位越來越重要。</div><div>　　LED封裝用苯基硅油主要包括端乙烯基甲基硅油和苯基氫硅油。根據苯含量，苯基硅油可分為低苯基硅油(5%-10%苯基摩爾)、中苯基硅油(25%苯基摩爾)、高苯基硅油(45%苯基摩爾)。不同用途的LED封裝膠對苯基含量的要求不同。大功率LED封裝膠一般需要較高的苯基含量來達到高折射率，從而減少光源的能量損耗。</div><div>　　乙烯基封端甲基苯基硅油是指主鏈以乙烯基封端的硅原子連接甲基硅油和苯基硅油。按苯基的類型可分為甲基苯基鏈節型、二苯基鏈節型和混合型(同時含有兩條苯基鏈)。</div><div>　　含氫苯基硅油分為端氫苯基硅油和側含氫苯基硅油，用途不同。前者主要用作包裝膠的稀釋劑或擴鏈劑，后者主要用作包裝膠的集中交聯劑，起交聯中間的作用。含苯基和氫的硅油的制備方法是陽離子聚合，一般使用硫酸。為了減少工藝流程，酸性樹脂也可用于催化聚合，省去了中和催化劑的步驟，直接過濾酸性樹脂，酸性樹脂可重復使用。</div><div>　　乙烯基甲基苯基硅油和苯基氫硅油是制作高折射率LED封裝膠的基礎原料。隨著LED產業的快速發展，LED封裝行業潛力無限，對苯基硅油的需求也是很大的。近年來，隨著我國苯基單體及中間體生產技術的進一步提高，該類產品的研究取得了一定進展，但與國外產品相比仍有一定差距，亟待改進。目前，國外有機硅公司壟斷了高折射率LED封裝膠的制備技術和市場。苯基材料是發展的關鍵，也是急需研究的要點。</div> 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