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class="typo"> 　　苯基硅油成分<br />　　苯基硅油是一種無色或淡黃色的透明油，是甲基硅油中部分甲基被苯基取代的產物。不僅甲基硅油可以用于織物，合成苯基硅油對織物也有影響。本文合成了幾種苯基硅油，并測試了苯基硅油及其組成的硅橡膠體系的綜合性能。研究了用于織物處理的不同苯基硅油的性能，分析了處理前后織物的性能和變化。<br />　　由甲基三甲氧基硅烷合成了高純度甲基苯基二甲氧基硅烷。以六甲基二硅氧烷為封端劑，三氟甲磺酸為催化劑，全共水解后，通過平衡縮合得到不同苯基摩爾含量的甲基苯基硅油和二苯基硅油。<br />　　研究了兩種苯基硅油的苯基摩爾含量對硅油熱穩定性、折射率和流變性能的影響。結果表明，對于二苯基硅油，當苯基的摩爾分數為40%時，折射率達到1.5435，當苯基的摩爾分數為30%時，熱穩定性好。<br />　　以二苯基二甲氧基硅烷和二甲基二甲氧基硅烷為原料，1，3-二乙烯基四甲基二硅氧烷為封端劑，制備了乙烯基封端苯基硅油。以二苯基二甲氧基硅烷、二甲基二甲氧基硅烷和甲基二氯硅烷為原料，六甲基二硅氧烷為封端劑，合成了苯基含氫硅油。<br />　　乙烯基封端的苯基硅油和苯基含氫硅油在催化劑的作用下交聯固化得到硅橡膠。制備的薄膜在460納米紫外光下的大透光率可達97.14%。探索了不同苯基硅油組成的苯基硅橡膠體系的性能變化規律，發現苯基硅橡膠的折射率與乙烯基封端苯基硅油的分子量呈正相關。<br />　　將幾種苯基硅油應用于織物處理，并對其力學性能、白度等進行了測試。對比測試了處理前后織物的牢度和苯基硅油處理后織物的牢度。研究發現，苯基硅油整理后的織物拉伸強度普遍提高，但白度略有下降。經苯基硅油處理后的色布，皂洗牢度、濕摩擦牢度和耐光牢度均提高了一個等級。<br />　　甲基硅油用于織物的柔軟整理，增加織物的潤滑性、平滑性、豐滿性和彈性。但用苯基硅油整理后，織物的拉伸強度普遍提高，但白度略有下降。經苯基硅油處理后的色布，皂洗牢度、濕摩擦牢度和耐光牢度均提高了一個等級。 </div> </div> </div>  <div class="bot-mod-box mt10"> <div class="bot-mod-link"> <div class="bot-m-l"> <b>上一篇：</b> <a 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